How do you determine instrumental broadening?

You have to measure the FWHMsample of each peak of your sample (take into account only Ka1 if you don’t have Ka2 monochromator) and subtract the instrumental FWHMinst at that particular diffraction angle.

What is peak broadening in XRD?

Peak broadening in XRD depend mainly on how small the crystallite size of the sample powder is. The smaller the crystallite size, the broader the peak and vice versa. For the other question, Dr Marco Taddei has provided a good insight into peak splitting of a peak shoulder.

How do you analyze XRD peaks?

Some steps for performing qualitative analysis of an XRD sample are as follows:

1. Peak identification. The first part of data evaluation is to identify diffraction peaks. This involves several steps:
2. Phase identification. In powder diffraction the term phase is often used as a synonym for substance.

Can anyone explain the instrumental broadening of XRD peaks?

Generally, polymer has broadening XRD peaks, especial amorphous polymer. All diffractometers (and spectrometers) have their resolutions. You will not get any peak that has less width than the resolution width even if the signal has no width like a delta function.

Why does peak broadening occur in Xrd powder?

There are two different questions you asked here. Peak broadening in XRD depend mainly on how small the crystallite size of the sample powder is. The smaller the crystallite size, the broader the peak and vice versa. For the other question, Dr Marco Taddei has provided a good insight into peak splitting of a peak shoulder. Best wishes!

How can I remove instrument broadening in XRD analysis?

To obtain the instrumental FWHM function of the diffraction angle you can pass a commercial standard for XRD (LaB6 or Al2O3) to determine the FWHMinst. Then fit FWHMinst VS 2teta with a polynomial function. There are NIST Standards available to calculate Beta (instrument) whih is considered as instrumental factor.

What are the sources of peak broadening in X-ray?

B. The Sample Contribution. This arises from factors (T.Ungar in “Industrial Applications of X-ray Diffraction” eds: Chung & Smith, Marcel Dekker, New York, @2000, page 847) such as: crystallite/diffracting domain size